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In situ Raman and UV-vis spectroscopic studies of polypyrrole and poly(pyrrole-2,6-dimethyl-β-cyclodextrin).

Identifieur interne : 001362 ( Main/Exploration ); précédent : 001361; suivant : 001363

In situ Raman and UV-vis spectroscopic studies of polypyrrole and poly(pyrrole-2,6-dimethyl-β-cyclodextrin).

Auteurs : RBID : pubmed:21111671

English descriptors

Abstract

Polypyrrole (PPy) and poly(pyrrole-2,6-dimethyl-β-cyclodextrin) [P(Py-β-DMCD)] films prepared by potential cycling in aqueous acidic solutions on indium tin oxide (ITO)-coated glass and gold electrodes were studied by in situ UV-vis and Raman spectroscopy. Characteristic UV-vis and Raman bands were identified and their dependencies on the electrode potential have been discussed. Spectroelectrochemical results reveal differences both in the position of the spectral bands and their potential dependence for PPy and P(Py-β-DMCD) films indicating interactions between polymer chains and CDs during electropolymerization process. The films were also characterized by cyclic voltammetry and FT-IR spectroscopy.

DOI: 10.1016/j.saa.2009.12.026
PubMed: 21111671

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Le document en format XML

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<name sortKey="Arjomandi, Jalal" uniqKey="Arjomandi J">Jalal Arjomandi</name>
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<name sortKey="Shah, Anwar Ul Haq Ali" uniqKey="Shah A">Anwar-ul-Haq Ali Shah</name>
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<name sortKey="Bilal, Salma" uniqKey="Bilal S">Salma Bilal</name>
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<name sortKey="Van Hoang, Hung" uniqKey="Van Hoang H">Hung Van Hoang</name>
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<name sortKey="Holze, Rudolf" uniqKey="Holze R">Rudolf Holze</name>
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<term>Spectroscopy, Fourier Transform Infrared</term>
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<div type="abstract" xml:lang="en">Polypyrrole (PPy) and poly(pyrrole-2,6-dimethyl-β-cyclodextrin) [P(Py-β-DMCD)] films prepared by potential cycling in aqueous acidic solutions on indium tin oxide (ITO)-coated glass and gold electrodes were studied by in situ UV-vis and Raman spectroscopy. Characteristic UV-vis and Raman bands were identified and their dependencies on the electrode potential have been discussed. Spectroelectrochemical results reveal differences both in the position of the spectral bands and their potential dependence for PPy and P(Py-β-DMCD) films indicating interactions between polymer chains and CDs during electropolymerization process. The films were also characterized by cyclic voltammetry and FT-IR spectroscopy.</div>
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